Rhodia offers 5 kinds of high temperature silicone resins, most of which are phenyl silicone resins.
· Methyl silicone resin (a small amount of phenyl) - Resin 10336
· Four benzyl silicone resins—Resin 6405, 6407, 6482, 10312, 10369
· Applied to continuous coating of building materials—Resin 10369
Advice/Recommendation
Fast drying: Resin 10336, fast drying, reduces drying speed and drying time; although it is methyl resin, the thermal adhesion of its coating is very good, with a proper formula, the heat resistance temperature can reach 400 ℃ .
High thermal stability: Resin 10312 is the most flexible resin among these resins. It has outstanding thermal stability in industrial coatings with a heat-resistant temperature of 600°C or above.
The best overall performance: Resin 6405, which has both flexibility, hardness and thermal stability, the coating produced can be cured after drying in air.
High Solids Coatings: Resin 6407, a silicone resin with higher molecular weight and higher silicone content than Resin 6405.
Wide range of adaptability: Resin 6482, due to its highly reactive hydroxyl groups, this resin is used for cold blending with silicone binders (alkyds, acrylics and epoxies) to improve their performance at high temperatures gloss and crack resistance.
Typical performance:
Product grade |
10336 |
6405 |
6407 |
6482 |
10312 |
||
group |
methyl |
methylphenyl |
methylphenyl |
methylphenyl |
methylphenyl |
||
Solid content % |
50 |
50 |
70 |
60 |
50 |
||
Flash point |
Toluene °C |
- |
4 |
4 |
15 |
7 |
|
Xylene °C |
25 |
24 |
- |
28 |
25 |
||
Density@25℃ |
1.04 |
1.01 |
1.09 |
1.06 |
1.00 |
||
Viscosity@25℃ |
40 |
50 |
70 |
15 |
170 |
||
The content of hydroxyl groups in organosilicon % by weight |
- |
- |
3.5 |
4.2 |
- |
||
Compatibility with Silicone Resins |
- |
+ |
+ |
++ |
+ |
||
Appearance of the cross-linked film |
Smooth and glossy |
Smooth and glossy |
Smooth and glossy |
Smooth and glossy |
Smooth and glossy |
||
Pendulum hardness test (NET30016) |
@20℃, s |
220 |
210 |
210 |
210 |
55 |
|
@200℃, s |
60 |
50 |
50 |
115 |
45 |
||
Flexibility Deep Drawing Experiment, min (NET30019) |
6 |
5 |
6 |
4 |
5 |
||
Shock, cm (ASTM D 2794) |
40 |
40 |
40 |
0 |
80 |
||
Cracking resistance@300℃, h |
- |
>1000 |
>1000 |
- |
>1000 |
||
Steel Adhesion Test, % (NET 30038) |
100 |
100 |
100 |
100 |
100 |
Coating Formulation
After a given pigment:binder ratio (P:B) has been selected, the paint is prepared as follows: The filler and pigment are added to the binder, while any additional solvent (toluene or xylene) is added to adjust its viscosity , using a suitable grinding machine, preferably explosion-proof equipment, and adding certain additives at the end of grinding:
-PDMS v 100
- Sylosiva A 4 (prevents volatilization of gas during paint storage)
-Bentone 34 (thixotropic agent)
When applied, the coating can be diluted with xylene to a viscosity suitable for equipment such as a spray applicator.
Example: 100 Basic Aluminum/Zinc Recipe
Resin 6405 or 10336 |
57 |
Alpate 101 |
19 |
Zinc powder |
9.5 P:B=1:1 |
Extra Steamic O |
9.5 |
Sylosiv A 4 |
1 |
Xylene |
4 |
-3# rotor, 5rpm viscosity, 600mPa/sec
-3# rotor, speed 100rpm, viscosity, 450mPa/sec
202 Zinc-rich paint
Resin 6405 |
10 |
Zinc powder |
84 P:B=19 |
Sylosiv A 4 |
1 |
Xylene |
5 |
-3# rotor, 5rpm viscosity, 18000mPa/sec
-3# rotor, speed 100rpm, viscosity, 3300mPa/sec
203 aluminum coating
Resin 6405 |
45 |
Alpate 101 |
45 P:B=1.3 |
Sylosiv A 4 |
2 |
Xylene |
8 |
-6# rotor, 5rpm viscosity, 12000mPa/sec
-6# rotor, speed 100rpm, viscosity, 5200mPa/sec
204 Matte Black Paint
Resin 6405 |
45.5 |
Zinc powder |
13 |
Black iron oxide 303T |
13 P:B=2 |
325 mesh mica powder |
13 |
Xylene |
15.5 |
-5# rotor, speed 5rpm, viscosity, 30000mPa/sec
-5# rotor, speed 100rpm, viscosity, 3500mPa/sec
205 Matte Black Paint 2#
Resin 6405 |
35 |
Titanium dioxide RL60 |
14 |
Black iron oxide 303T |
3.5 |
Busan 11 M1 |
17.5 P:B=2.6 |
Extra Steamic O |
7 |
325 mesh mica powder |
3.5 |
Xylene |
19.5 |
206 brown black paint
Resin 6405 |
18 |
Zinc powder |
49 |
Brown Iron Oxide 645T |
15 P:B=9.6 |
10%Bentone 34 gel in xylene |
2.5 |
Xylene |
15.5 |
This coating has very good resistance to salt spray and temperature resistance up to 600°C
207 dark red
Resin 6405 |
46.4 |
Red Iron Oxide 130F |
20 |
Zinc chromate |
4 |
Zinc oxide |
4 |
Barium sulfate |
12 |
Xylene |
13.6 |
The coating formulation has excellent corrosion protection properties
208 white paint
Resin 6405 |
45 |
Titanium oxide RL60 |
13.5 |
Busan 11 M 1 |
18 |
Extra Steamic O |
9 P:B=2.3 |
325 mesh mica powder |
4.5 |
Xylene |
10 |
The paint turns yellow only slightly above 1000°C
209 green filler
Resin 6842 |
46 |
ceramic powder |
31.5 |
chrome green |
4.5 |
red iron oxide |
0.3 |
manganese dioxide |
0.1 |
Aluminum stearate |
0.2 P:B=1.7 |
325 mesh mica powder |
6 |
Kaolin |
5 |
Butanol |
1.4 |
Toluene |
2.3 |
Xylene |
2.7 |
The coating is recommended for use at 500°C, for higher temperatures, 6405 or 10312 is recommended
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