Vertellus Polycins® Castor Oil Modified Polyol D-290 T-400 M365 D1000 D2000… Bio-based Hydrolysis Resistant Heat Resistant Polyol - 广州昊毅新材料科技股份有限公司

Castor Oil Products

Vertellus Polycins® Castor Oil Modified Polyol D-290 T-400 M365 D1000 D2000… Bio-based Hydrolysis Resistant Heat Resistant Polyol

                                                    

 

  Product introduction 
      Ventrus Specialties offers a new line of castor oil derived, low cost, 100% solids polyurethane polyols.
These new polyols are named POLYCIN® D, T and M series. These hydroxyl-terminated ricinoleate derivatives react with standard chemical isocyanates to form urethanes for coatings, adhesives, sealants, elastomers (CASE).

 

  Product Features
       Excellent electrical properties, low vapor hazard, easy handling, low viscosity, excellent permeability, room temperature curing, anti-reversion properties, thermal stability;
  Low heat release, low stress, low temperature resistance, excellent moisture retention, low cost, 100% solids content, no volatile organic compounds (VOC)

 

   Hydrolytic stability
    Polyurethane systems synthesized with POLYCINS® exhibit very good resistance to heat and humidity under any conditions. For example, systems based on POLYCINS® not only pass but also exceed the requirements of Navy avionics testing for 28 days at 95% relative humidity and 100°C.

 

· Low heat release
 Electronic components such as toroids, reeds, mercury switches, inductors, and selenium rectifiers are sensitive to stresses caused by packaging materials, which can cause changes in performance or even damage to components. The thermal sensitivity of electronic components and the avoidance of mechanical deformation require their low exotherm. Polyurethane systems are synthesized with POLYCINS® to meet requirements for low exotherm at an average temperature of 85°F (29.4°C) above ambient.

 

· Minimal shrinkage  
    Room temperature cured POLYCIN® elastomers show little or no shrinkage. This maintains the performance integrity of the finished system or product.

 

 · Temperature stability
     Test data show that POLYCIN® elastomers have significant thermal stability. Therefore, they guarantee a wide operating temperature range with a maximum interval temperature of 150°C.

 

· Chemical and solvent resistance
       The volume resistivity of the POLYCIN® system did not change after 6 months of exposure to seawater. The POLYCIN® Elastomers were immersed in 10% hydrochloric acid and sodium hydroxide solutions for 7 days respectively, completely unaffected.
The POLYCIN® system has excellent solvent resistance to aliphatic products (petroleum, heptane) and hydroxyl-containing materials (ethylene glycol). After 7 days of immersion at room temperature, there was little or no change in linear dimensions. However, when using an aromatic solvent (xylene), an oxygenated solvent (acetone), and a chlorinated solvent (tetrachloroethylene), there may be some linear expansion after standing at room temperature for 3 hours.

· Reactive diluents
   In polyurethane resin systems, POLYCINS® provides an excellent means of reducing volatile organic compounds (VOCs) and reducing viscosity. At the same time, it also has performance in improving hardness, elasticity, gloss, fluidity and wetness.

Security and Handling
       POLYCINS® is non-toxic, biodegradable, and produced from renewable resources. Under normal storage conditions, its shelf life is at least two years.

 

  physical properties

Typical performance

DB®Oil

D-120

D-140

D-265

D-290

T-400

Viscosity@25℃, cP

720

490

650

370

280

1,500

color, Gardner

2

3

2

2

3

3

Acidity

0.8

3

1

2

3

1

Hydroxyl value

164

125

140

265

290

400

equivalent

342

450

400

212

193

141

Specific Gravity@25℃

0.959

0.940

0.957

0.968

0.960

0,996

Density, lbs/gal

7.98

7.82

7.96

8.05

7.99

8.29

Moisture, %

0.02

0.02

0.02

0.02

0.02

0.02

functionality

2.7

2

2

2

2

3

Typical performance

M-280

M-365

D1000

D2000

D3000

D4000

Viscosity@25℃, cP

1,250

2,000

300

1,360

3,860

8,600

color, Gardner

3

3

4

7

8

11

Acidity

1

1

3

3

3

3

Hydroxyl value

280

365

123

54

38

28

equivalent

200

154

456

1039

1476

2004

Specific Gravity@25℃

0.990

1.02

-

-

-

-

Density, lbs/gal

8.24

8.49

-

-

-

-

Moisture, %

0.02

0.02

0.01

0.01

0.01

0.01

functionality

4

4+

2

2

2

2

 

  Coating properties

physical test

DB®0il

D-120

D-140

D-265

D-290

T-400

M-280

M-365

7 days pencil hardness

2B

HB

2B

HB

H

HB

HB

Direct shock, 140 lbs

pass

pass

pass

pass

pass

pass

pass

Reverse shock, 140 lbs

pass

pass

pass

pass

pass

120

pass

200 butanone rubbed twice

pass

pass

pass

pass

pass

pass

pass

Sodium hydroxide 50%

P

P

P

P

P

P

P

Toluene

F

P

P

P

P

P

P

acetic acid

F

F

F

F

F

F

F

brake fluid

F

P

P

F

P

P

P

water

P

P

P

P

P

P

P

Note: NCO:OH=1.05:1.0HDT P=Pass F=Fail

 

  Adhesive, Sealant and Elastomer (ASE) Properties  

physical test

DB®0il

D-120

D-140

D-265

D-290

T-400

Shore A hardness

75

41

45

100

100

100

Shore D hardness

25

14

70

74

81

stretch, psi

495

113

225

3200

4650

7600

Elongation, %

80

60

185

135

200

15

physical test

M-280

M-365

D1000

D2000

D3000

D4000

Shore A hardness

100

100

42

16

16

15

Shore D hardness

77

82

 

 

 

 

stretch, psi

5750

8100

150

40

39

43

Elongation, %

20

10

70

75

70

65

Note: MDI is cured at NCO/OH=1.05/1.0
c

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